Kinetic Modeling of Jet Propellant-10 Pyrolysis
نویسندگان
چکیده
منابع مشابه
Kinetic Modeling, Simulation, and Optimization of Pyrolysis
Thermal decomposition of organic matter under inert atmospheric conditions, leading to the release of volatiles and formation of cha is called as pyrolysis. It is also a first step in the biomass gasification. To design of a suitable pyrolysis reactor, understanding of kinetic parameters is essential. In the proposed kinetic model of this study, biomass decomposition is represented as a decompo...
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Pyrolysis essentially is the thermal decomposition of organic matter under inert atmospheric conditions or in a limited supply of air, leading to the release of volatiles and formation of char. Modeling of pyrolysis implies the representation of the chemical and physical phenomena in a mathematical form. In this study, Differential Evolution (DE) algorithm is applied and global optimum set of k...
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In order to investigate the initiation mechanisms and kinetics associated with the pyrolysis of JP-10 (exo-tricyclo[5.2.1.0(2,6)]decane), a single-component hydrocarbon jet fuel, we carried out molecular dynamics (MD) simulations employing the ReaxFF reactive force field. We found that the primary decomposition reactions involve either (1) dissociation of ethylene from JP-10, resulting in the f...
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Biomass is a versatile material. It can be directly combusted to produce heat; however, by first subjecting it to a thermal or biological degradation, it can also be converted to products with a higher heating value or to materials with properties superior to those of the raw material [1]. When heated in the absence of oxygen, biomass decomposes into a range of products; including char (solid),...
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Pyrolysis of residues from the oil extraction process of two types of microalgae, Chlamydomonas (C. sp. JSC4) and Chlorella sorokiniana (C. Sorokiniana CY1) was studied by means of a thermogravimetric analyzer. Five pseudo-components (hemicellulose, cellulose, lignin, lipid and protein) model with n=1 or n#1 was assumed for a kinetic analysis of the collected pyrolysis data. The model with n#1 ...
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ژورنال
عنوان ژورنال: Energy & Fuels
سال: 2014
ISSN: 0887-0624,1520-5029
DOI: 10.1021/ef502274r